Bis(acetato-κO)[1,2-bis(2-pyridylmethoxy)benzene-κ4 N,O,O′,N′]copper(II) tetrahydrate
نویسندگان
چکیده
In the title compound, [Cu(CH(3)COO)(2)(C(18)H(16)N(2)O(2))]·4H(2)O, the Cu(II) ion is six-coordinated in a Jahn-Teller-distorted octa-hedral geometry environment defined by four O atoms and two N atoms. A chain structure along [100] is built up by inter-molecular O-H⋯O hydrogen bonds involving the uncoordinated water mol-ecules.
منابع مشابه
[1,2-Bis(2-pyridylmethoxy)benzene-κ4 N,O,O′,N′]bis(nitrato-κO)copper(II)
In the title compound, [Cu(NO(3))(2)(C(18)H(16)N(2)O(2))], the Cu(II) ion is six-coordinated in a Jahn-Teller-distorted octa-hedral environment defined by two O and two N atoms from the ligand and two O atoms from two monodentate nitrate anions.
متن کاملBis(acetato-κO)[1,2-bis(2-pyridylmethoxy)benzene-κ4 N,O,O′,N′]copper(II) monohydrate
In the title compound, [Cu(CH(3)COO)(2)(C(18)H(16)N(2)O(2))]·H(2)O, the Cu(II) ion is six-coordinated in a typically Jahn-Teller distorted octa-hedral environment defined by two O and two N atoms from the ligand and two O atoms from acetate anions. A linear chain structure propagating in [010] is built up by inter-molecular O-H⋯O hydrogen bonds involving the uncoordinated water mol-ecules.
متن کامل{N,N′-Bis[1-(2-pyridyl)ethylidene]ethane-1,2-diamine-κ4 N,N′,N′′,N′′′}bis(trifluoromethanesulfanato-κO)copper(II)
A discrete neutral Cu(II) complex, [Cu(CF(3)SO(3))(2)(C(16)H(18)N(4))], has been derived from the symmetrical tetra-dentate Schiff base, N,N'-bis-[1-(pyridin-2-yl)ethyl-idene]ethane-1,2-diamine. The copper centre assumes a tetra-gonally distorted pseudo-octa-hedral geometry with the O atoms of two trifluoro-methane-sulfonate anions coordinated weakly in the axial positions. The Cu-N distances l...
متن کاملBis[4-amino-3,5-bis(pyridin-2-yl)-4H-1,2,4-triazole-κ2 N 2,N 3]bis(benzene-1,2-dicarboxylic acid-κO)copper(II) bis(2-carboxybenzoate)
In the complex cation of the title salt, [Cu(C(12)H(10)N(6))(2)(C(8)H(6)O(4))(2)](C(8)H(5)O(4))(2), the Cu(II) atom, lying on an inversion center, exhibits a distorted octa-hedral geometry defined by four N atoms from two 4-amino-3,5-bis-(pyridin-2-yl)-4H-1,2,4-triazole ligands in the equatorial plane and two axial O atoms from two benzene-1,2-dicarb-oxy-lic acid ligands. In the crystal, the co...
متن کامل[1,2-Bis(pyridin-2-ylmethoxy)benzene-κ4 N,O,O′,N′]bis(nitrato-κO)cobalt(II)
In the title compound, [Co(NO(3))(2)(C(18)H(16)N(2)O(2))], the Co(II) ion is six-coordinated in a distorted octa-hedral environment defined by two O and two N atoms from the ligand and by two O atoms from two nitrate anions. A two-dimensional network parallel to the ab plane is built up by C-H⋯O hydrogen bonds, which link adjacent mol-ecules in the crystal structure.
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010